Genesis 10:10 -
And the beginning of his kingdom was Babel, and Erech, and Accad, and Calneh, in the land of Shinar.
Amos 6:2
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Pass ye unto Calneh, and see; and from thence go ye to Hamath the great: then go down to Gath of the Philistines: be they better than these kingdoms? or their border greater than your border?